dc.description.abstract |
CuBiS2 bulkswerepreparedbyreactivesinteringthemixtureofCu2S andBi2S3 at 300,350,400,and
450 °C for2handatthesinteringtemperatureof400 °C for1,1.5,2,2.5,and3hunderacompensation
disc ofCuSforatmosphericcontrol.Composition,structure,morphology,andelectricalpropertiesofthe
sinteredbulkswereanalyzed.ThecompositionsofCu,Bi,andSdidnotchangeuntilthetemperature
reached at450 °C.The highestelectricalconductivityof4.3Scm 1 and thehighestHallmobilityof
11.1cm2 V 1 s 1 wereobtainedforCuBiS2 sinteredat400 °C for2h.ThedeviationintheS/(CuþBi)
ration causedthedegradationofelectricalproperties,thoughtheCuBiS2 remained asasinglephase.
Therefore,CuBiS2, alessstudiedternarycopperbasedsulfide, isthe p-type semiconductorforpotential
energy-relatedapplicationandneedstohaveagoodcontrolincomposition. |
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